(E)-3-Hydroxy-13-methyl-16-[4-(methylsulfanyl)benzylidene]-7,8,9,11,12,13,15,16-octahydro-6H-cyclopenta[a]phenanthren-17(14H)-one
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چکیده
In the title compound, C(26)H(28)O(2)S, the dihedral angles between the mean plane of the five membered ring and the 4-(methyl-sulfan-yl)benzyl-idine ring in the two crystallographically independent mol-ecules are 34.05 (10) and 40.53 (15)°. The packing is stabilized by inter-molecular O-H⋯O and C-H⋯O inter-actions.
منابع مشابه
4-Methyl-1-[4-(methylsulfanyl)benzylidene]thiosemicarbazide
The title compound, C(10)H(13)N(3)S(2), is roughly planar (r.m.s. deviation = 0.086 Å). In the crystal, N-H⋯S hydrogen bonds link the mol-ecules into (001) sheets.
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In the title compound, C(38)H(36)N(3)O(2)S(2)·CH(2)Cl(2), the 2-oxindole ring is almost planar (r.m.s. deviation = 0.032 Å), the pyrrolidine ring adopts a twist conformation and the piperidone ring exists as a chair. Three short C-H⋯O intra-molecular contacts occur. In the crystal, mol-ecules are linked by C-H⋯O and C-H⋯N inter-actions. The dichloro-methane solvent mol-ecule is disordered over ...
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